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Author(s):   Gordon, A.S.; Smith, S.R.; Drew, C.M.
Title:   Photolysis of mixtures of cyclobutane and acetone-d6. Reactions of the cyclobutyl radical
Journal:   J. Chem. Phys.
Volume:   36
Year:   1962
Reference type:   Journal article
Squib:   1962GOR/SMI824

Reaction:   Cyclobutane + CD3CHD3 + Cyclobutyl
Reaction order:   2
Reference reaction:   (CD3)2CO + CD3 → Other Products + CD4
Reference reaction order:   2
Temperature:   535 - 675 K
Pressure:  1.00E-1 - 0.15 bar
Rate expression:   1.3 e4057 [J/mole]/RT
Bath gas:   Cyclobutane
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
535 3.24E0
550 3.16E0
575 3.04E0
600 2.93E0
625 2.84E0
650 2.75E0
675 2.68E0