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Title: Ultraviolet absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase
Journal: Chem. Rev.
Volume: 92
Page(s): 667 - 710
Year: 1992
Reference type: Journal article
Squib: 1992WAL/DAG667-710
Reaction:
NO2 + CCl3O2 → CCl3OONO2
Reaction order:
2
Temperature:
233 - 373
K
Rate expression:
5.99x10-12 [±1.01x10-12 cm3/molecule s] (T/298 K)(-2.50±1.00)
Category: Review
Data type:
Extensive literature review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 233 | 1.11E-11 |
| 250 | 9.30E-12 |
| 275 | 7.33E-12 |
| 300 | 5.90E-12 |
| 325 | 4.83E-12 |
| 350 | 4.01E-12 |
| 373 | 3.42E-12 |