 |
Home ©NIST, 2023 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Physicochemical properties of chlorine oxides. 1. Composition, ultraviolet spectrum, and kinetics of the thermolysis of gaseous dichlorine hexoxide
Journal: J. Phys. Chem.
Volume: 94
Page(s): 3860 - 3863
Year: 1990
Reference type: Journal article
Squib: 1990LOP/SIC3860-3863
Reaction:
Cl2O6 → O2 + Cl2O4
Reaction order:
1
Temperature:
293 - 303
K
Pressure: 6.67E-4 - 1.60E-3 bar
Rate expression:
2.51x1011 [s-1] e-86471 [±6901 J/mole]/RT
Uncertainty:
20.0
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 293 | 9.65E-5 |
| 300 | 2.21E-4 |
| 303 | 3.11E-4 |