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Title: Thermolytic Reactions of Esters. Part VI. A Study on the Steric and Polar Nature of the β-Elimination Mechanism
Journal: Rec. Trav. Chim. Pays/Bas
Volume: 91
Page(s):
Year: 1972
Reference type: Journal article
Squib: 1972TIN/KOO3
Reaction:
CF3C(O)OC(CH3)2C2H5 → CF3COOH + (CH3)2C=CHCH3
Reaction order:
1
Temperature:
477 - 529
K
Rate expression:
1.1x1011 [s-1] e-133863 [±8032 J/mole]/RT
Uncertainty:
5.0
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 477 | 2.41E-4 |
| 500 | 1.14E-3 |
| 525 | 5.28E-3 |
| 529 | 6.66E-3 |