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Accessibility information
Author(s):   Tinkelenberg, A.; Kooyman, E.C.; Louw, R.
Title:   Thermolytic Reactions of Esters. Part VI. A Study on the Steric and Polar Nature of the β-Elimination Mechanism
Journal:   Rec. Trav. Chim. Pays/Bas
Volume:   91
Year:   1972
Reference type:   Journal article
Squib:   1972TIN/KOO3

Reaction:   CF3C(O)OC(CH3)2C2H5CF3COOH + (CH3)2C=CHCH3
Reaction order:   1
Temperature:   477 - 529 K
Rate expression:   1.1x1011 [s-1] e-133863 [±8032 J/mole]/RT
Uncertainty:   5.0
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
477 2.41E-4
500 1.14E-3
525 5.28E-3
529 6.66E-3