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Accessibility information
Author(s):   Manion, J.A.; Tsang, W.
Title:   Hydrogen atom attack on fluorotoluenes: Rates of fluorine displacement
Journal:   Isr. J. Chem.
Volume:   36
Page(s):   263 - 273
Year:   1996
Reference type:   Journal article
Squib:   1996MAN/TSA263-273

Reaction:   2-Fluorotoluene + Fluorobenzene + ·CH3
Reaction order:   2
Reference reaction:   1,3,5-Trimethylbenzene + 1,3-Dimethylbenzene + ·CH3
Reference reaction order:   2
Temperature:   988 - 1142 K
Pressure:  2.00 - 2.50 bar
Rate expression:   3.54x10-1±4.3x10-2 e1147 [±407 J/mole]/RT
Uncertainty:   1.39999998
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
988 4.07E-1
1000 4.06E-1
1025 4.05E-1
1050 4.04E-1
1075 4.02E-1
1100 4.01E-1
1125 4.00E-1
1142 3.99E-1