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Title: Arrhenius parameters for the reaction of trifluoromethyl radicals with cyanogen chloride
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 77
Page(s): 253 - 260
Year: 1977
Reference type: Journal article
Squib: 1977COS/OEX253-260
Reaction:
ClCN + ·CF3 → CN + CF3Cl
Reaction order:
2
Temperature:
268 - 693
K
Pressure: 0.13 - 0.35 bar
Rate expression:
2.14x10-11 [cm3/molecule s] e-48640 [J/mole]/RT
Bath gas:
CF3I
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 268 | 7.09E-21 |
| 275 | 1.24E-20 |
| 300 | 7.28E-20 |
| 325 | 3.26E-19 |
| 350 | 1.18E-18 |
| 375 | 3.60E-18 |
| 400 | 9.53E-18 |
| 425 | 2.25E-17 |
| 450 | 4.84E-17 |
| 475 | 9.60E-17 |
| 500 | 1.78E-16 |
| 525 | 3.10E-16 |
| 550 | 5.15E-16 |
| 575 | 8.17E-16 |
| 600 | 1.25E-15 |
| 625 | 1.84E-15 |
| 650 | 2.64E-15 |
| 675 | 3.69E-15 |
| 693 | 4.62E-15 |