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Author(s):   Shum, L.G.S.; Benson, S.W.
Title:   The pyrolysis of dimethyl sulfide, kinetics and mechanism
Journal:   Int. J. Chem. Kinet.
Volume:   17
Year:   1985
Reference type:   Journal article
Squib:   1985SHU/BEN749

Reaction:   CH3CH2S → CH2CH2SH
Reaction order:   1
Temperature:   681 - 723 K
Rate expression:   2.0x1013 [s-1] e-133863 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
681 1.08E3
700 2.05E3
723 4.27E3