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Author(s):   Khachatryan, L.; Burcat, A.; Dellinger, B.
Title:   The Role of Chlorine Atoms and Hydroxyl Radicalsin the Formation of PCDDs from the Oxidative Pyrolysis of 2,4,6-Trichlorophenol
Journal:   Int. J. Chem. Kinet.
Volume:   42
Page(s):   90 - 97
Year:   2010
Reference type:   Journal article
Squib:   2010KHA/BUR90-97

Reaction:   C5Cl3H2 → C3HCl2 + HCCCl
Reaction order:   1
Temperature:   750 - 1075 K
Rate expression:   6.14x10-13 [s-1] e-125520 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Pressure dependence:   None reported
Comments:   Estimated based on rate constants for non-chlorinated cyclopentadienyl radicals.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
750 1.11E-21
775 2.13E-21
800 3.92E-21
825 6.94E-21
850 1.19E-20
875 1.97E-20
900 3.19E-20
925 5.02E-20
950 7.71E-20
975 1.16E-19
1000 1.71E-19
1025 2.47E-19
1050 3.50E-19
1075 4.89E-19