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Accessibility information
Author(s):   Chuchani, G.; Dominguez, R.M.
Title:   Kinetics of the Gas-Phase Elimination of α-Bromophenylacetic Acid Under Maximum Inhibition
Journal:   Int J. Chem. Kinet.
Volume:   31
Page(s):   725 - 728
Year:   1999
Reference type:   Journal article
Squib:   1999CHU/DOM725-728

Reaction:   C6H5CHBrCOOH → Benzaldehyde + HBr
Reaction order:   1
Temperature:   533 - 588 K
Pressure:  2.67E-2 - 9.33E-2 bar
Rate expression:   1.7x1012 [s-1] e-164900 [±2700 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
533 1.20E-4
550 3.71E-4
575 1.78E-3
588 3.85E-3