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Author(s):   Alwe, H. D.; Walavalkar, M. P.; Sharma, A.; Dhanya, S.; Naik, P. D.
Title:   Tropospheric oxidation of cyclic unsaturated ethers in the day-time: Comparison of the reactions with Cl, OH and O3 based on the determination of their rate coefficients at 298 K
Journal:   Atmos. Environ.
Volume:   82
Page(s):   113 - 120
Year:   2014
Reference type:   Journal article
Squib:   2014ALW/WAL113-120

Reaction:   3,4-Dihydro-2H-pyran + ·Cl → Products
Reaction order:   2
Reference reaction:   1-C6H14 + ·Cl → Products
Temperature:   298 K
Pressure:  1.07 bar
Rate expression:   6.02x10-10 [±8.3x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   The error quoted is a combination of the 2σ error of the rate constant ratio and the reported error of the rate constant of the reference reaction, both combined using the statistical error propagation equation.

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