 |
Home ©NIST, 2022 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Free radical addition to olefins. Part 8. Addition of n-heptafluoropropyl radicals to fluoro-ethylenes
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 68
Page(s): 160 - 166
Year: 1972
Reference type: Journal article
Squib: 1972TED/WAL160-166
Reaction:
CF3CF2CF2I + CHF2CF: → CF3CF2CF2CFHCF2I
Reaction order:
2
Reference reaction:
CH2=CF2 + CF3CF2CF2I → CF3CF2CF2CH2CF2I
Reference reaction order:
2
Temperature:
315 - 475
K
Pressure: 6.13E-2 bar
Rate expression:
2.75 e-1588 [±923 J/mole]/RT
Uncertainty:
1.04999995
Bath gas:
CF3CF2CF2I
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 315 | 1.50E0 |
| 325 | 1.53E0 |
| 350 | 1.59E0 |
| 375 | 1.65E0 |
| 400 | 1.71E0 |
| 425 | 1.75E0 |
| 450 | 1.80E0 |
| 475 | 1.84E0 |