Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Setser, D.W.; Rabinovitch, B.S.
Title:   Thermal unimolecular geometric and structural isomerization of 1,2-dideuterio-3-methylcyclopropane
Journal:   J. Am. Chem. Soc.
Volume:   86
Page(s):   564 - 569
Year:   1964
Reference type:   Journal article
Squib:   1964SET/RAB564-569

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1964SET/RAB564-569   Cyclopropane-2,3-d2-cis-trans, 1-methyl-cis- → Cyclopropane-2,3-d2-trans-trans, 1-methyl-cis-  653 - 693   2.51E15       2.54E05      1
  1964SET/RAB564-569   Cyclopropane-2,3-d2-cis-trans, 1-methyl-cis- → Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis-  653 - 693   2.00E15       2.53E05      1
  1964SET/RAB564-569   Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → Products  693 - 748   2.69E14       2.61E05      1
  1964SET/RAB564-569   Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → CH2DC(CH3)=CHD  693 - 748   0.10              1
  Reference reaction:  Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → Products 1
  1964SET/RAB564-569   Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → 2-Butene-1,2,d2, cis  693 - 748   0.17              2
  Reference reaction:  Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → Products 2
  1964SET/RAB564-569   Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → 2-Butene-1,2-d2, trans  693 - 748   0.07              1
  Reference reaction:  Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → Products 1
  1964SET/RAB564-569   Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → 1-Butene-1,3-d2, trans  693 - 748   0.20              1
  Reference reaction:  Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → Products 1
  1964SET/RAB564-569   Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → CHD=CDCH2CH3  693 - 748   0.20              1
  Reference reaction:  Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → Products 1
  1964SET/RAB564-569   Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → CHD2CH=CHCH3-(E)  693 - 748   0.07              2
  Reference reaction:  Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → Products 2
  1964SET/RAB564-569   Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → CHD2CH==CHCH3-(Z)  693 - 748   0.17              1
  Reference reaction:  Cyclopropane-2,3-d2-cis-cis, 1-methyl-cis- → Products 1
  1964SET/RAB564-569   Methylcyclopropane1-C4H8  693 - 748   0.46              1
  Reference reaction:  Methylcyclopropane → Products 1
  1964SET/RAB564-569   MethylcyclopropaneIsobutene  693 - 748   0.08              1
  Reference reaction:  Methylcyclopropane → Products 1
  1964SET/RAB564-569   Methylcyclopropane(Z)-2-C4H8  693 - 748   0.33              1
  Reference reaction:  Methylcyclopropane → Products 1
  1964SET/RAB564-569   Methylcyclopropane(E)-2-C4H8  693 - 748   0.14              1
  Reference reaction:  Methylcyclopropane → Products 1

Search returned 14 records.