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Accessibility information
Author(s):   Kairaitis, D.A.; Stimson, V.R.
Title:   The thermal decompositions of ethyl trans-crotonate and ethyl n-butyrate
Journal:   Aust. J. Chem.
Volume:   21
Page(s):   1349 - 1354
Year:   1968
Reference type:   Journal article
Squib:   1968KAI/STI1349-1354

Reaction:   (E)-CH3CH=CHCOOC2H5C2H4 + (E)-CH3CH=CHCOOH
Reaction order:   1
Temperature:   633 - 693 K
Rate expression:   1.78x1012 [s-1] e-196222 [J/mole]/RT
Bath gas:   (E)-CH3CH=CHCOOC2H5
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
633 1.14E-4
650 3.04E-4
675 1.16E-3
693 2.89E-3