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Author(s):   Tsang, W.; Mokrushin, V.
Title:   Mechanism and rate constants for 1,5-butadiene decomposition
Journal:   Proc. Combust. Inst.
Volume:   28
Page(s):   1717 - 1723
Year:   2000
Reference type:   Journal article
Squib:   2000TSA/MOK1717-1723

Reaction:   1,2-butadiene·CH3 + CH2=C=CH
Reaction order:   1
Temperature:   1200 - 1800 K
Pressure:  1.00 bar
Rate expression:   2.69x1036 [s-1] (T/298 K)-20.83 e-510509 [J/mole]/RT
Category:  Theory
Data type:   Derived from fitting to a complex mechanism

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1200 4.05E1
1250 1.34E2
1300 3.92E2
1350 1.03E3
1400 2.44E3
1450 5.33E3
1500 1.08E4
1550 2.04E4
1600 3.64E4
1650 6.13E4
1700 9.83E4
1750 1.51E5
1800 2.22E5