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Title: Mechanism and rate constants for 1,5-butadiene decomposition
Journal: Proc. Combust. Inst.
Volume: 28
Page(s): 1717 - 1723
Year: 2000
Reference type: Journal article
Squib: 2000TSA/MOK1717-1723
Reaction:
1,2-butadiene → ·CH3 + CH2=C=CH
Reaction order:
1
Temperature:
1200 - 1800
K
Pressure: 1.00 bar
Rate expression:
2.69x1036 [s-1] (T/298 K)-20.83 e-510509 [J/mole]/RT
Category: Theory
Data type:
Derived from fitting to a complex mechanism
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1200 | 4.05E1 |
| 1250 | 1.34E2 |
| 1300 | 3.92E2 |
| 1350 | 1.03E3 |
| 1400 | 2.44E3 |
| 1450 | 5.33E3 |
| 1500 | 1.08E4 |
| 1550 | 2.04E4 |
| 1600 | 3.64E4 |
| 1650 | 6.13E4 |
| 1700 | 9.83E4 |
| 1750 | 1.51E5 |
| 1800 | 2.22E5 |