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Title: Mechanism and rate constants for 1,5-butadiene decomposition
Journal: Proc. Combust. Inst.
Volume: 28
Page(s): 1717 - 1723
Year: 2000
Reference type: Journal article
Squib: 2000TSA/MOK1717-1723
Reaction:
1,3-Butadiene → 1,2-butadiene
Reaction order:
1
Temperature:
1200 - 1800
K
Pressure: 1.00 bar
Rate expression:
7.86x1031 [s-1] (T/298 K)-17.56 e-484484 [J/mole]/RT
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1200 | 1.53E0 |
| 1250 | 5.20E0 |
| 1300 | 1.57E1 |
| 1350 | 4.25E1 |
| 1400 | 1.05E2 |
| 1450 | 2.38E2 |
| 1500 | 5.00E2 |
| 1550 | 9.85E2 |
| 1600 | 1.83E3 |
| 1650 | 3.21E3 |
| 1700 | 5.37E3 |
| 1750 | 8.59E3 |
| 1800 | 1.32E4 |