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Author(s):   Tsang, W.; Mokrushin, V.
Title:   Mechanism and rate constants for 1,5-butadiene decomposition
Journal:   Proc. Combust. Inst.
Volume:   28
Page(s):   1717 - 1723
Year:   2000
Reference type:   Journal article
Squib:   2000TSA/MOK1717-1723

Reaction:   1,2-butadiene1,3-Butadiene
Reaction order:   1
Temperature:   1200 - 1800 K
Pressure:  1.00 bar
Rate expression:   1.09x1037 [s-1] (T/298 K)-20.85 e-555906 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1200 1.68E0
1250 6.65E0
1300 2.30E1
1350 7.03E1
1400 1.93E2
1450 4.82E2
1500 1.11E3
1550 2.35E3
1600 4.67E3
1650 8.72E3
1700 1.54E4
1750 2.59E4
1800 4.16E4