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Title: Mechanism and rate constants for 1,5-butadiene decomposition
Journal: Proc. Combust. Inst.
Volume: 28
Page(s): 1717 - 1723
Year: 2000
Reference type: Journal article
Squib: 2000TSA/MOK1717-1723
Reaction:
1,2-butadiene → 1,3-Butadiene
Reaction order:
1
Temperature:
1200 - 1800
K
Pressure: 1.00 bar
Rate expression:
1.09x1037 [s-1] (T/298 K)-20.85 e-555906 [J/mole]/RT
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1200 | 1.68E0 |
| 1250 | 6.65E0 |
| 1300 | 2.30E1 |
| 1350 | 7.03E1 |
| 1400 | 1.93E2 |
| 1450 | 4.82E2 |
| 1500 | 1.11E3 |
| 1550 | 2.35E3 |
| 1600 | 4.67E3 |
| 1650 | 8.72E3 |
| 1700 | 1.54E4 |
| 1750 | 2.59E4 |
| 1800 | 4.16E4 |