NIST Chemical Kinetics Database

Author(s):   Huybrechts, G.; Meyers, L.; Verbeke, G.
Title:   Stability and reactions of the tetrachloroethyl radical
Journal:   Trans. Faraday Soc.
Volume:   58
Page(s):
Year:   1962
Reference type:   Journal article
Squib:   1962HUY/MEY1128

Reaction:   CCl₃CHCl → C₂HCl₃ + ·Cl
Reaction order:   1
Temperature:   433 - 497 K
Pressure:  8.00E-2 - 0.15 bar
Rate expression:   5.01x10¹¹ [s^-1] e^{-85639 [±4265 J/mole]/RT}
Uncertainty:   3.1600000858306885
Bath gas:   Cl2
Category: Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [s^-1]
433	2.34E1
450	5.75E1
475	1.92E2
497	5.00E2