NIST Chemical Kinetics Database

Author(s):   Olbregts, J.
Title:   Competitive chlorination-dehydrochlorination of 1,1,1,2-C₂H₂Cl₄
Journal:   Int. J. Chem. Kinet.
Volume:   11
Page(s):   117 - 124
Year:   1979
Reference type:   Journal article
Squib:   1979OLB117-124

Reaction:   CCl₃CHCl → C₂HCl₃ + ·Cl
Reaction order:   1
Temperature:   349 - 404 K
Pressure:  6.67E-2 - 0.17 bar
Rate expression:   3.98x10¹¹ [s^-1] e^{-68594 [±8314472 J/mole]/RT}
Uncertainty:   5.0
Bath gas:   CH2ClCCl3
Category: Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Pressure measurement

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [s^-1]
349	2.16E1
350	2.31E1
375	1.11E2
400	4.39E2
404	5.39E2