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Author(s):   Benson, S.W.; Weissman, M.
Title:   Mechanism of the pyrolysis of C2HCl5, molecular and radical steps
Journal:   Int. J. Chem. Kinet.
Volume:   14
Page(s):   1287 - 1304
Year:   1982
Reference type:   Journal article
Squib:   1982BEN/WEI1287-1304

Reaction:   CCl3CHCl → C2HCl3 + ·Cl
Reaction order:   1
Temperature:   300 - 700 K
Rate expression:   2.51x1013 [s-1] e-69842 [±16047 J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 1.74E1
325 1.50E2
350 9.48E2
375 4.69E3
400 1.90E4
425 6.55E4
450 1.96E5
475 5.24E5
500 1.27E6
525 2.82E6
550 5.85E6
575 1.14E7
600 2.09E7
625 3.65E7
650 6.13E7
675 9.89E7
700 1.54E8