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Author(s):   Yang, X.L.; Kiefer, J.H.; Tranter, R.S.
Title:   Thermal dissociation of ethylene glycol vinyl ether
Journal:   Phys. Chem. Chem. Phys.
Volume:   13
Page(s):   21288 - 21300
Year:   2011
Reference type:   Journal article
Squib:   2011YAN/KIE21288-21300

Reaction:   Ethylene glycol monovinyl ether + ·OHCH2=CHOH + CH2=CHO· + H2O
Reaction order:   1
Temperature:   1200 - 1800 K
Rate expression:   1.03x10-13 [s-1] (T/298 K)4.00 e-4182 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Pressure dependence:   Rate constant is pressure independent
Comments:   Estimated based on group parameters from the literature.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1200 1.79E-11
1250 2.14E-11
1300 2.54E-11
1350 3.00E-11
1400 3.52E-11
1450 4.10E-11
1500 4.75E-11
1550 5.47E-11
1600 6.28E-11
1650 7.17E-11
1700 8.15E-11
1750 9.23E-11
1800 1.04E-10