 |
Home ©NIST, 2022 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: An experimental and theoretical investigation of the formation of C7H7 isomers in the bimolecular reaction of dicarbon molecules with 1,3-pentadiene
Journal: Chem. Phys. Lett.
Volume: 607
Page(s): 92 - 99
Year: 2014
Reference type: Journal article
Squib: 2014DAN/PAR92-99
Reaction:
CH2=CHCH=CHCH3 + C2 → Products
Reaction order:
2
Rate expression:
no rate data available
Category: Experiment
Data type:
Mechanistic information only
Pressure dependence:
None reported
Experimental procedure:
Molecular beam
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
By end product analysis
Analytical technique:
Mass spectrometry
Comments:
The reaction involves indirect scattering dynamics initiated by the barrierless addition of dicarbon to the carbon–carbon double bond of 1,3-pentadiene followed by successive rearrangements leading eventually through hydrogen atom elimination to distinct C7H7 radical species.
View full bibliographic record.