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Accessibility information
Author(s):   Wampler, F.B.; Kuntz, R.R.
Title:   Some hydrogen abstraction reactions of the CF3CCl2 radical
Journal:   Int. J. Chem. Kinet.
Volume:   3
Page(s):  
Year:   1971
Reference type:   Journal article
Squib:   1971WAM/KUN483

Reaction:   Methylcyclohexane + CF3CCl2 → Other Products + CF3CHCl2
Reaction order:   2
Reference reaction:   CF3CCl2 + CF3CCl2(CF3CCl2)2
Temperature:   369 - 434 K
Pressure:  0.29 bar
Rate expression:   7.42x10-13 [cm3/molecule s] e-38496 [±1538 J/mole]/RT
Uncertainty:   1.70000005
Bath gas:   Methylcyclohexane
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
369 2.64E-18
375 3.22E-18
400 6.98E-18
425 1.38E-17
434 1.73E-17