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Author(s):   Bryukov, M.G.; Slagle, I.R.; Knyazev, V.D.
Title:   Kinetics of Reactions of H Atoms with Ethane and Chlorinated Ethanes
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   6900 - 6909
Year:   2001
Reference type:   Journal article
Squib:   2001BRY/SLA6900-6909

Reaction:   CH3CCl3 + → Products
Reaction order:   2
Temperature:   358 - 850 K
Pressure:  2.44E-3 - 1.07E-2 bar
Rate expression:   1.83x10-10 [±6.2x10-11 cm3/molecule s] e-29533 [±1272 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Analytical technique:   Resonance fluorescence
Comments:   Error limits (2?igma? reflect only statistical contributions.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
358 8.98E-15
375 1.41E-14
400 2.55E-14
425 4.29E-14
450 6.83E-14
475 1.03E-13
500 1.50E-13
525 2.11E-13
550 2.87E-13
575 3.80E-13
600 4.91E-13
625 6.23E-13
650 7.75E-13
675 9.49E-13
700 1.14E-12
725 1.36E-12
750 1.61E-12
775 1.87E-12
800 2.16E-12
825 2.47E-12
850 2.80E-12