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Author(s):   Anson, P.C.; Fredricks, P.S.; Tedder, J.M.
Title:   Free-radical substitution in aliphatic compounds. Part I. Halogenation of n-Butane and isoButane in the gas phase
Journal:   J. Chem. Soc. A
Year:   1959
Reference type:   Journal article
Squib:   1959ANS/FRE918

Reaction:   iso-C4H10 + ·Cltert-C4H9 + HCl
Reaction order:   2
Reference reaction:   iso-C4H10 + ·Cliso-C4H9 + HCl
Reference reaction order:   2
Temperature:   263 - 419 K
Rate expression:   2.1 e2253 [±8314472 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
263 5.88E0
275 5.63E0
300 5.18E0
325 4.83E0
350 4.55E0
375 4.33E0
400 4.13E0
419 4.01E0