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Author(s):   Knox, J.H.; Nelson, R.L.
Title:   Competitive chlorination reactions in the gas phase: hydrogen and C1-C5 saturated hydrocarbons
Journal:   Trans. Faraday Soc.
Volume:   55
Year:   1959
Reference type:   Journal article
Squib:   1959KNO/NEL937

Reaction:   iso-C4H10 + ·Cltert-C4H9 + HCl
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Reference reaction order:   2
Temperature:   193 - 593 K
Pressure:  0.67 bar
Rate expression:   1.8x10-1 e4265 [±170 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
193 2.57E0
200 2.34E0
225 1.76E0
250 1.40E0
275 1.16E0
300 9.95E-1
325 8.73E-1
350 7.80E-1
375 7.07E-1
400 6.49E-1
425 6.02E-1
450 5.63E-1
475 5.30E-1
500 5.02E-1
525 4.78E-1
550 4.57E-1
575 4.39E-1
593 4.28E-1