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Author(s):   Smith, J.D.; DeSain, J.D.; Taatjes, C.A.
Title:   Infrared Laser Absorption Measurements of HCl(v=1) Production in Reactions of Cl Atoms with Isobutane, Methanol, Acetaldehyde, and Toluene at 295 K
Journal:   Chem. Phys. Lett.
Volume:   366
Page(s):   417 - 425
Year:   2002
Reference type:   Journal article
Squib:   2002SMI/DES417-425

Reaction:   iso-C4H10 + ·Cltert-C4H9 + HCl
Reaction order:   2
Temperature:   295 K
Pressure:  1.33E-2 bar
Rate expression:   1.49x10-10 [±2.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   IR absorption
Comments:   193 nm photolysis of CF2Cl2 / IR laser absorption of HCl, branching into HCl (v=1) also given when buffer is Ar (rate coefficients used CO2), a large portion of the available energy partitions into HCl vibration, results are constent with a direct H atom abstraction

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