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Author(s):   Glover, B.G.; Miller, T.A.
Title:   Near-IR cavity ringdown spectroscopy and kinetics of the isomers and conformers of the butyl peroxy radical
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   11191 - 11197
Year:   2005
Reference type:   Journal article
Squib:   2005GLO/MIL11191-11197

Reaction:   iso-C4H10 + ·Cltert-C4H9 + HCl
Reaction order:   2
Reference reaction:   iso-C4H10 + ·Cliso-C4H9 + HCl
Reference reaction order:   2
Temperature:   298 K
Pressure:  0.31 bar
Rate expression:   9.0
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   193-nm photolysis of (COCl)2 used as source of Cl atoms.
Yield of specific butyl radicals based on isomer specific yields of butyl peroxul radicals determined by cavity ringdown spectroscopy.

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