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Author(s):   Pritchard, H.O.; Pyke, J.B.; Trotman-Dickenson, A.F.
Title:   The study of chlorine atom reactions in the gas phase
Journal:   J. Am. Chem. Soc.
Volume:   77
Year:   1955
Reference type:   Journal article
Squib:   1955PRI/PYK2629

Reaction:   iso-C4H10 + ·Cl → Other Products + HCl
Reaction order:   2
Reference reaction:   C2H6 + ·Cl·C2H5 + HCl
Temperature:   298 - 484 K
Pressure:  9.87E-2 - 0.22 bar
Rate expression:   3.25x10-10 [cm3/molecule s] e-3592 [J/mole]/RT
Bath gas:   C2H6
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 7.64E-11
300 7.71E-11
325 8.61E-11
350 9.47E-11
375 1.03E-10
400 1.11E-10
425 1.18E-10
450 1.25E-10
475 1.31E-10
484 1.33E-10