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Title: Disproportionation-Combination Ratios in Thermalized Cyclic Radical Systems. Rate of Isomerization of Pent-2-en-5-yl Radical
Journal: Int. J. Chem. Kinet.
Volume: 7
Page(s):
Year: 1975
Reference type: Journal article
Squib: 1975STE/RAB531
Reaction:
CH2=CHCH2CH2· + Cyclobutyl → 1-C4H8 + Cyclobutene
Reaction order:
2
Reference reaction:
CH2=CHCH2CH2· + Cyclobutyl → Adduct
Reference reaction order:
2
Temperature:
298
K
Pressure: 1.33E-2 - 1.33 bar
Rate expression:
3.0x10-1±9.0x10-2
Bath gas:
H2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Sensitized photolysis
Analytical technique:
Gas chromatography
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