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Author(s):   Anderson, P.N.; Hites, R.A.
Title:   OH radical reactions: the major removal pathway for polychlorinated biphenyls from the atmosphere
Journal:   Environ. Sci. Technol.
Volume:   30
Page(s):   1756 - 1763
Year:   1996
Reference type:   Journal article
Squib:   1996AND/HIT1756-1763

Reaction:   1,1'-Biphenyl, 2-chloro- + ·OH → Products
Reaction order:   2
Reference reaction:   iso-C4H10 + ·OH → Other Products + H2O
Temperature:   343 - 363 K
Pressure:  1.01 bar
Rate expression:   7.31x10-12 [cm3/molecule s] e-2494 [±1821 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
343 3.05E-12
350 3.10E-12
363 3.20E-12