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Title: Chemical kinetic data base for combustion chemistry. Part 4. Isobutane
Journal: J. Phys. Chem. Ref. Data
Volume: 19
Page(s): 1 - 68
Year: 1990
Reference type: Journal article
Squib: 1990TSA1-68
Reaction:
tert-C4H9 + ·C2H5 → C2H4 + iso-C4H10
Reaction order:
2
Temperature:
300 - 2500
K
Rate expression:
5.1x10-12 [cm3/molecule s] (T/298 K)-0.75
Uncertainty:
2.0
Category: Review
Data type:
Extensive literature review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 300 | 5.07E-12 |
| 400 | 4.09E-12 |
| 500 | 3.46E-12 |
| 600 | 3.02E-12 |
| 700 | 2.69E-12 |
| 800 | 2.43E-12 |
| 900 | 2.23E-12 |
| 1000 | 2.06E-12 |
| 1100 | 1.91E-12 |
| 1200 | 1.79E-12 |
| 1300 | 1.69E-12 |
| 1400 | 1.60E-12 |
| 1500 | 1.52E-12 |
| 1600 | 1.45E-12 |
| 1700 | 1.38E-12 |
| 1800 | 1.32E-12 |
| 1900 | 1.27E-12 |
| 2000 | 1.22E-12 |
| 2100 | 1.18E-12 |
| 2200 | 1.14E-12 |
| 2300 | 1.10E-12 |
| 2400 | 1.07E-12 |
| 2500 | 1.03E-12 |