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Accessibility information
Author(s):   Rao, V.S.; Skinner, G.B.
Title:   Formation of H and D atoms in pyrolysis of benzene-d6, chlorobenzene, bromobenzene, and iodobenzene behind shock waves
Journal:   J. Phys. Chem.
Volume:   92
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988RAO/SKI2442

Reaction:   Benzene-d, 4-bromo- → Br· + Phenyl-4-d
Reaction order:   1
Temperature:   1500 - 1900 K
Pressure:  0.41 bar
Rate expression:   1.54x1013 [s-1] e-300984 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1500 5.09E2
1525 7.56E2
1550 1.11E3
1575 1.61E3
1600 2.30E3
1625 3.26E3
1650 4.56E3
1675 6.33E3
1700 8.70E3
1725 1.18E4
1750 1.60E4
1775 2.14E4
1800 2.84E4
1825 3.74E4
1850 4.89E4
1875 6.35E4
1900 8.19E4