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Author(s):   Giri, B.R.; AlAbbad, M.; Barker, J.R.; Farooq, A.
Title:   High temperature unimolecular decomposition of cyclopentanone
Journal:   Proc. Combust. Inst.
Volume:   37
Page(s):   267 - 273
Year:   2019
Reference type:   Journal article
Squib:   2019GIR/ALA267-273

Reaction:   Cyclopentanone → Products
Reaction order:   1
Temperature:   1156 - 1571 K
Pressure:  1.00 - 2.40 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   IR absorption
Comments:   Carbon monoxide is one of the main reaction products and its formation was monitored using a quantum cascade laser operating near 4.56 μm. No Arrhenius expression is provided. Experimental values of the rate constants are given in a tabular format in the supporting information for the article.

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