Author(s):   Gray, P.; Herod, A.A.
Title:   Methyl radical reactions with isopropanol and methanol, their ethers and their deuterated derivatives
Journal:   Trans. Faraday Soc.
Volume:   64
Page(s):
Year:   1968
Reference type:   Journal article
Squib:   1968GRA/HER2723

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
1968GRA/HER2723	CH₃OH + ·CH₃ → Other Products + CH₄	413 - 523	3.02E-13	4.11E04	2
1968GRA/HER2723	iso-C₃H₇OH + ·CH₃ → Other Products + CH₄	408 - 523	1.59E-13	3.05E04	2
1968GRA/HER2723	(iso-C₃H₇)2O + ·CH₃ → CH₄ + (CH₃)2CHC(O)(CH₃)2	408 - 523	2.41E-13	3.29E04	2
1968GRA/HER2723	Dimethyl ether + ·CH₃ → CH₄ + CH₃OCH₂·	408 - 523	6.92E-13	4.18E04	2
1968GRA/HER2723	CH₃OD + CD₃ → CD₄ + CH₃O·	413 - 523	5.25E-14	4.73E04	2
1968GRA/HER2723	CH₃OD + CD₃ → CHD₃ + CH₂OD	413 - 523	9.43E21	4.21E04	2
1968GRA/HER2723	CD₃OH + ·CH₃ → CH₄ + CD₃O	408 - 523	5.25E-14	3.97E04	2
1968GRA/HER2723	CD₃OH + ·CH₃ → CH₃D + CD₂OH	408 - 523	3.64E-13	4.99E04	2
1968GRA/HER2723	CD₃ + iso-C₃H₇CHOD → Other Products + CHD₃	408 - 523	2.46E-13	3.31E04	2
1968GRA/HER2723	CD₃ + iso-C₃H₇CHOD → CD₄ + (CH₃)2CHO·	408 - 523	2.24E-15	2.52E04	2
1968GRA/HER2723	·CH₃ + 2-Propan-2-d-ol → Other Products + CH₄	408 - 523	8.14E-14	3.77E04	2
1968GRA/HER2723	·CH₃ + 2-Propan-2-d-ol → CH₃D + (CH₃)2C(·)OH	408 - 523	3.17E-13	4.06E04	2

Search returned 12 records.