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Title: Ultraviolet absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase
Journal: Chem. Rev.
Volume: 92
Page(s): 667 - 710
Year: 1992
Reference type: Journal article
Squib: 1992WAL/DAG667-710
Reaction:
CH3O2· + CH3C(O)OO(·) → CH2O + CH3C(O)OH + O2
Reaction order:
2
Temperature:
298 - 368
K
Rate expression:
4.1x10-15 [cm3/molecule s] e17460 [J/mole]/RT
Category: Review
Data type:
Extensive literature review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 4.71E-12 |
| 300 | 4.50E-12 |
| 325 | 2.63E-12 |
| 350 | 1.65E-12 |
| 368 | 1.23E-12 |