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Author(s):   Fettis, G.C.; Knox, J.H.; Trotman-Dickenson, A.F.
Title:   The reactions of bromine atoms with alkanes and methyl halides
Journal:   J. Chem. Soc. A
Year:   1960
Reference type:   Journal article
Squib:   1960FET/KNO4177

Reaction:   iso-C4H10 + Br·tert-C4H9 + HBr
Reaction order:   2
Reference reaction:   CH3Br + Br· → Products
Temperature:   423 - 483 K
Rate expression:   3.34x10-11 [cm3/molecule s] e-31429 [±940 J/mole]/RT
Uncertainty:   1.28999996
Bath gas:   Br2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
423 4.39E-15
425 4.58E-15
450 7.51E-15
475 1.17E-14
483 1.33E-14