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Author(s):   Choo, K.Y.; Choe, M.H.
Title:   A kinetic study of Br atom reactions with trimethylsilane by the VLPR (very low pressure reactor) technique
Journal:   Bull. Korean Chem. Soc.
Volume:   6
Year:   1985
Reference type:   Journal article
Squib:   1985CHO/CHO196

Reaction:   iso-C4H10 + Br·tert-C4H9 + HBr
Reaction order:   2
Temperature:   299 - 328 K
Rate expression:   6.61x10-11 [cm3/molecule s] e-29267 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
299 5.10E-16
300 5.30E-16
325 1.31E-15
328 1.44E-15