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Author(s):   Benson, S.W.; Kondo, O.; Marshall, R.M.
Title:   Absolute rate constants for the reaction of Br atoms with i-C4H10
Journal:   Int. J. Chem. Kinet.
Volume:   19
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987BEN/KON829

Reaction:   iso-C4H10 + Br·tert-C4H9 + HBr
Reaction order:   2
Temperature:   298 - 363 K
Pressure:  1.33E-3 bar
Rate expression:   4.15x10-11 [cm3/molecule s] e-28020 [±2519 J/mole]/RT
Uncertainty:   2.50999999
Bath gas:   He
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 5.09E-16
300 5.49E-16
325 1.30E-15
350 2.73E-15
363 3.86E-15