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Title: Homogeneous Decomposition of Vinyl Ethers. The Heat of Formation of Ethanal-2-yl
Journal: Int. J. Chem. Kinet.
Volume: 11
Page(s):
Year: 1979
Reference type: Journal article
Squib: 1979ROS/GOL715
Reaction:
CH2=CHOC2H5 → C2H4 + CH3CHO
Reaction order:
1
Temperature:
750 - 1050
K
Rate expression:
2.95x1011 [s-1] e-181255 [±3633 J/mole]/RT
Uncertainty:
1.77999997
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 750 | 7.02E-2 |
| 775 | 1.79E-1 |
| 800 | 4.32E-1 |
| 825 | 9.86E-1 |
| 850 | 2.15E0 |
| 875 | 4.46E0 |
| 900 | 8.92E0 |
| 925 | 1.72E1 |
| 950 | 3.19E1 |
| 975 | 5.75E1 |
| 1000 | 1.01E2 |
| 1025 | 1.71E2 |
| 1050 | 2.84E2 |