Author(s):   Fenske, J.D.; Hasson, A.S.; Ho, A.W.; Paulson, S.E.
Title:   Measurement of Absolute Unimolecular and Bimolecular Rate Constants for CH₃CHOO Generated by the trans-2-Butene Reaction with Ozone in the Gas Phase
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   9921 - 9932
Year:   2000
Reference type:   Journal article
Squib:   2000FEN/HAS9921-9932

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	k(298.00 K)	Order
2000FEN/HAS9921-9932	(E)-2-C₄H₈ + O₃ → Other Products + CH₃CHO	298	1.90E-16	1.90E-16	2
2000FEN/HAS9921-9932	CH₃CHO + CH₃CH(·)OO· → CH₃CH(O₂)OCHCH₃	298	1.00E-12	1.00E-12	2
2000FEN/HAS9921-9932	CH₃CH(O₂)OCHCH₃ → Products	298	76.00	76.00	2

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