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Author(s):   Fenske, J.D.; Hasson, A.S.; Ho, A.W.; Paulson, S.E.
Title:   Measurement of Absolute Unimolecular and Bimolecular Rate Constants for CH3CHOO Generated by the trans-2-Butene Reaction with Ozone in the Gas Phase
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   9921 - 9932
Year:   2000
Reference type:   Journal article
Squib:   2000FEN/HAS9921-9932

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2000FEN/HAS9921-9932   (E)-2-C4H8 + O3 → Other Products + CH3CHO  298   1.90E-16           1.90E-16  2
  2000FEN/HAS9921-9932   CH3CHO + CH3CH(·)OO· → CH3CH(O2)OCHCH3  298   1.00E-12           1.00E-12  2
  2000FEN/HAS9921-9932   CH3CH(O2)OCHCH3 → Products  298   76.00           76.00  2

Search returned 3 records.