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Author(s):   Hynes, A.J.; Steinberg, M.; Schofield, K.
Title:   The chemical kinetics and thermodynamics of sodium species in oxygen-rich hydrogen flames
Journal:   J. Chem. Phys.
Volume:   80
Page(s):   2585 - 2597
Year:   1984
Reference type:   Journal article
Squib:   1984HYN/STE2585-2597

Reaction:   Na + O2NaO2
Reaction order:   3
Temperature:   1650 - 2400 K
Rate expression:   6.7x10-31 [cm6/molecule2 s] (T/298 K)-1.00
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Laser induced fluorescence

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
1650 1.21E-31
1700 1.17E-31
1750 1.14E-31
1800 1.11E-31
1850 1.08E-31
1900 1.05E-31
1950 1.02E-31
2000 9.98E-32
2050 9.74E-32
2100 9.51E-32
2150 9.29E-32
2200 9.08E-32
2250 8.87E-32
2300 8.68E-32
2350 8.50E-32
2400 8.32E-32