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Author(s):   Plane, J.M.C.
Title:   A comparison between the oxidation reactions of the alkali and alkaline earth atoms
Page(s):   29 - 56
Year:   1992
Book Title:   Gas-Phase Metal Reactions,
Publisher:   ed. A. Fontijn
Publisher address:   pub. Elsevier Science Publ., Amsterdam, Netherlands
Reference type:   Book Chapter
Squib:   1992PLA29-56C

Reaction:   Na + O2NaO2
Reaction order:   3
Temperature:   233 - 1120 K
Pressure:  5.33E-3 - 0.13 bar
Rate expression:   2.9x10-30 [±6.89x10-31 cm6/molecule2 s] (T/298 K)(-1.30±0.70)
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
233 3.99E-30
250 3.64E-30
300 2.87E-30
350 2.35E-30
400 1.97E-30
450 1.69E-30
500 1.48E-30
550 1.31E-30
600 1.17E-30
650 1.05E-30
700 9.54E-31
750 8.72E-31
800 8.02E-31
850 7.41E-31
900 6.88E-31
950 6.41E-31
1000 6.00E-31
1050 5.63E-31
1100 5.30E-31
1120 5.18E-31