Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Iwasaki, E.; Nakayama, T.; Matsumi, Y.; Takahashi, K.; Wallington, T.J.; Hurley, M.D.; Kaiser, E.W.
Title:   Kinetics and mechanism of the reaction of chlorine atoms with n-pentanal
Journal:   J. Phys. Chem. A
Volume:   112
Page(s):   1741 - 1746
Year:   2008
Reference type:   Journal article
Squib:   2008IWA/NAK1741-1746

Reaction:   Pentanoyl chloride + ·Cl → Products
Reaction order:   2
Reference reaction:   C2H4 + ·Cl → Products
Reference reaction order:   2
Temperature:   295 K
Pressure:  0.93 bar
Rate expression:   9.3x10-1±9.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Vis-UV emission

View full bibliographic record.