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Author(s):   Iwasaki, E.; Nakayama, T.; Matsumi, Y.; Takahashi, K.; Wallington, T.J.; Hurley, M.D.; Kaiser, E.W.
Title:   Kinetics and mechanism of the reaction of chlorine atoms with n-pentanal
Journal:   J. Phys. Chem. A
Volume:   112
Page(s):   1741 - 1746
Year:   2008
Reference type:   Journal article
Squib:   2008IWA/NAK1741-1746

Reaction:   Pentanoyl chloride + ·Cl → Products
Reaction order:   2
Temperature:   295 K
Pressure:  0.93 bar
Rate expression:   8.74x10-11 [±1.38x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Vis-UV emission
Comments:   The rate constant was measured relative to reactions: Cl+C2H4 and Cl+Cyclohexane

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