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Title: Kinetics of CH2OO reactions with SO2, NO2, NO, H2O and CH3CHO as a function of pressure
Journal: Phys. Chem. Chem. Phys.
Volume: 16
Page(s): 1139 - 1149
Year: 2014
Book Title: ''
Editor: ''
Publisher: ''
Publisher address: ''
Comments: ''
Reference type: Journal article
Squib: 2014STO/BLI1139-1149
Reaction:
CH3CHO + CH2OO → 1,2,4-Trioxolane, 3-methyl-
Reaction order:
3
Reference reaction:
CH3CHO + CH2OO → CH2O + CH3C(O)OH
Reference reaction order:
2
Temperature:
295
K
Pressure: 3.33E-2 - 0.40 bar
Rate expression:
1.09x10-18 [±8.0x10-20 cm3/molecule]
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
Rate constant is low pressure limit
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
HCHO reaction product was monitored by laser-induced fluorescence. The rate constant ratio was obtaind from the slope of a Stern-Volmer plot. Errors are 1σ.
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