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Accessibility information
Author(s):   Atkinson, R.; Aschmann, S.M.; Winer, A.M.; Pitts, J.N., Jr.
Title:   Rate Constants for the Reaction of OH Radicals with a Series of Alkanes and Alkenes at 299 ± 2 K
Journal:   Int. J. Chem. Kinet.
Volume:   14
Page(s):  
Year:   1982
Reference type:   Journal article
Squib:   1982ATK/ASC507

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1982ATK/ASC507   C2H4 + ·OH → Products  299   8.49E-12              2
  1982ATK/ASC507   C2H4 + ·OHC2H3 + H2O  299   1.12              2
  Reference reaction:  Cyclohexane + ·OHCyclohexyl + H2O 2
  1982ATK/ASC507   CH2=C(CH3)CH=CH2 + ·OH → Products  299   9.60E-11              2
  1982ATK/ASC507   CH2=C(CH3)CH=CH2 + ·OH → Products  299   3.81              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1982ATK/ASC507   2,3-Dimethylbutane + ·OH → Other Products + H2O  299   6.26E-12              2
  1982ATK/ASC507   2,3-Dimethylbutane + ·OH → Other Products + H2O  299   0.83              2
  Reference reaction:  Cyclohexane + ·OHCyclohexyl + H2O 2
  1982ATK/ASC507   1-C4H10 + ·OH → Other Products + H2O  299   2.57E-12              2
  1982ATK/ASC507   1-C4H10 + ·OH → Other Products + H2O  299   0.45              2
  Reference reaction:  1-C6H14 + ·OH → Products 2
  1982ATK/ASC507   1-C4H10 + ·OH → Other Products + H2O  299   0.34              2
  Reference reaction:  Cyclohexane + ·OHCyclohexyl + H2O 2
  1982ATK/ASC507   1-C6H14 + ·OH → Other Products + H2O  299   5.71E-12              2
  1982ATK/ASC507   Cyclohexane + ·OHCyclohexyl + H2O  299   7.52E-12              2
  1982ATK/ASC507   Cyclohexane + ·OHCyclohexyl + H2O  299   1.32              2
  Reference reaction:  1-C6H14 + ·OH → Products 2
  1982ATK/ASC507   CH3CH=CH2 + ·OH → Products  299   2.52E-11              2
  1982ATK/ASC507   Cyclopentane + ·OHCyclopentyl + H2O  299   5.33E-12              2
  1982ATK/ASC507   Cyclopentane + ·OHCyclopentyl + H2O  299   0.70              2
  Reference reaction:  Cyclohexane + ·OHCyclohexyl + H2O 2
  1982ATK/ASC507   neo-C5H12 + ·OHNeopentyl + H2O  299   7.69E-13              2
  1982ATK/ASC507   neo-C5H12 + ·OHNeopentyl + H2O  299   0.14              2
  Reference reaction:  1-C6H14 + ·OH → Products 2
  1982ATK/ASC507   (CH3)2C=CHCH3 + ·OH → Products  299   8.63E-11              2
  1982ATK/ASC507   (CH3)2C=CHCH3 + ·OH → Products  299   3.43              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1982ATK/ASC507   (CH3)2C=C(CH3)2 + ·OH → Products  299   1.08E-10              2
  1982ATK/ASC507   (CH3)2C=C(CH3)2 + ·OH → Products  299   4.28              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2

Search returned 21 records.