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Author(s):   Baasandorj, M.; Fleming, E.L.; Jackman, C.H.; Burkholder, J.B.
Title:   O(D-1) Kinetic Study of Key Ozone Depleting Substances and Greenhouse Gases
Journal:   J. Phys. Chem. A
Volume:   117
Page(s):   2434 - 2445
Year:   2013
Reference type:   Journal article
Squib:   2013BAA/FLE2434-2445

Reaction:   O(1D) + CFCl3 → Products
Reaction order:   2
Temperature:   217 - 373 K
Pressure:  4.67E-2 bar
Rate expression:   2.39x10-10 [±2.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   This is the total O(1D) disappearance rate constant, which includes reaction and quenching. Uncertainties in this work at the 2σ level from the precision of the measurement.

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