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Title: O(D-1) Kinetic Study of Key Ozone Depleting Substances and Greenhouse Gases
Journal: J. Phys. Chem. A
Volume: 117
Page(s): 2434 - 2445
Year: 2013
Reference type: Journal article
Squib: 2013BAA/FLE2434-2445
Reaction:
O(1D) + CH3CF3 → Products
Reaction order:
2
Reference reaction:
O(1D) + CHF2Cl → Products
Reference reaction order:
2
Temperature:
296
K
Pressure: 0.24 bar
Rate expression:
4.9x10-1±1.0x10-2
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
This rate constant represents the reactive channel only, with quenching excluded. Uncertainties in this work at the 2σ level from the precision of the measurement.
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