 |
Home ©NIST, 2023 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: O(D-1) Kinetic Study of Key Ozone Depleting Substances and Greenhouse Gases
Journal: J. Phys. Chem. A
Volume: 117
Page(s): 2434 - 2445
Year: 2013
Reference type: Journal article
Squib: 2013BAA/FLE2434-2445
Reaction:
O(1D) + CF3CF2Cl → Products
Reaction order:
2
Temperature:
296
K
Pressure: 0.24 bar
Rate expression:
5.16x10-11 [±1.8x10-12 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
This rate constant represents the reactive channel only, with quenching excluded. The value is the average of three determinations, where NF3, CF3CHF2, and CHClF2 were used as reference compounds.
View full bibliographic record.