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Author(s):
Baasandorj, M.; Fleming, E.L.; Jackman, C.H.; Burkholder, J.B.
Title:
O(D-1) Kinetic Study of Key Ozone Depleting Substances and Greenhouse Gases
Journal:
J. Phys. Chem. A
Volume:
117
Page(s):
2434 - 2445
Year:
2013
Reference type:
Journal article
Squib:
2013BAA/FLE2434-2445
Reaction:
O(1D) + CF3CF2Cl → Products
Reaction order:
2
Temperature:
217 - 373
K
Pressure: 4.67E-2 bar
Rate expression:
6.5x10-11 [±7.0x10-12 cm3/molecule s] e249 [±249 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
This is the total O(1D) disappearance rate constant, which includes reaction and quenching. Uncertainties in this work at the 2σ level from the precision of the measurement.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
T (K) | k(T) [cm3/molecule s] |
217 |
7.46E-11 |
225 |
7.43E-11 |
250 |
7.33E-11 |
275 |
7.25E-11 |
300 |
7.18E-11 |
325 |
7.13E-11 |
350 |
7.08E-11 |
373 |
7.04E-11 |
|